Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Mildly toxic by skin contact. endstream
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5. swallowed. Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. : 93-58-3 1.2 Relevant identifi ed uses of the substance or mixture and uses advised against . It is the simplest diazo compound.In the pure form at room temperature, it is an extremely sensitive explosive yellow gas; thus, it is almost universally used as a solution in diethyl ether.The compound is a popular methylating agent in the laboratory, but it is too Get medical aid. IDENTIFICATION Product Description: METHYL BENZOATE FCC Precautions for safe handling Do not handle or store near an open flame, heat or other sources of ignition. Incompatible with strong acids, strong bases, nitrates, oxidizers. l5(K
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\Xd!z`pDO3Lh"DR H$#4!09 Precautionary Statements. Signal Word. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. When heated to decomposition, it emites fumes containing CO and CO2. Refer to Health & Safety and Technical notes section below for additional information. Handle in accordance with good industrial hygiene and safety practice. f Methyl Benzoate may cause a skin allergy and an asthma-like allergy. Sigma-Aldrich Corporation and its Affiliates shall not be . Precautionary Statements. 0000003105 00000 n
SODIUM BENZOATE 0.2% Sodium Benzoate. GSM: +968 9800 4222 May be harmful if Download COA. any substance or mixture of substances intended for preventing, destroying, or controlling any pest, including vectors of human or animal disease, unwanted species of plants or animals, causing harm during or otherwise interfering with the production, processing, storage, transport, or marketing of. 0000003831 00000 n
P301+P317 IF SWALLOWED: Get medical help. Slightly soluble in water. Cool this mixture by partially immersing the flask in an ice-water bath. Denser than water. . Esters react with acids to liberate heat along with alcohols and acids. if absorbed through the skin. f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. Rinse and then wash skin with water and soap. Methyl benzoate is an organic compound. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. (USCG, 1999) DuPont Tychem Suit Fabrics No . xSn0h
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b7&Rls3C!5p'ToVzYc][k-R^BDA%bQ-qx9e7?kyLn#8 7}+N'?tR2%::`1-- wmeQ=VpmWuSAt+3 Remove contaminated clothes. Follow this link for more information about how preservatives protect cosmetics and personal care products. It is used in perfume bases, such as ylang-ylang and tuberose types. M205-500 Discharge into the environment must be avoided. P376: Stop leak if safe to do so. [6] 1 Anasazi Experiment Series. Temperature:23.0C. GHS07. After completion stir for 5 more min. Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. a Weigh 2.0 g of methyl benzoate into a dry 50 cm3 conical flask. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Web site owner: i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. METHYL BENZOATE is an ester. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. 1 0 obj
Handling in a well ventilated place. Wash mouth out with water. . Diazepam rectal gel rectal delivery system is a non-sterile diazepam gel provided in a prefilled, unitdose, rectal delivery system. Procedure: For the best results, dosage should start at the first sign of an attack.Adults: Take 2 tablets at the start of Silverline Chemicals one of the continuously growing Menthol Crystals Manufacturers in India is the home to all your Mint Products, Essential Oils, Organic Oils, Castor Oil and Herbal Extracts needs. Fight fire with normal precautions from a reasonable distance. Propyl hydroxybenzoate (E216) 4mg/5ml. 0000008079 00000 n
4 0 obj
Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 (USCG, 1999). PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. stream
SAFETY DATA SHEET. e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. Fair Lawn, NJ 07410 state, and local environmental regulations must be This medicine contains 6.3 mg of sodium benzoate in each 5 ml, which is equivalent to 1.26 mg/ml. 40, FD&C Yellow No. May be harmful if swallowed. The ester group attached to the benzene ring of methyl benzoate. Hydrolyzes slowly in contact with water (NTP, 1992). endobj
P211: difficulty in urinating (dribbling) jerking movements. Avoid contact with skin and eyes. Office of Response and Restoration, c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube. startxref
Use in a well ventilated area. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. Sodium benzoate 25 mg. Propylene glycol 2.72 mg. For the full list of excipients, see section 6.1. stemmed pipet, over 3-4 minutes, to the methyl benzoate/sulfuric acid solution, which should still be kept cold in the ice bath and being continuously stirred. Slightly soluble in water. Product name : Methyl-p-Hydroxy Benzoate Sodium Salt CAS-No. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . SAFETY DATA SHEET Creation Date 18-Sep-2009 Revision Date 24-Dec-2021 Revision Number 6 1. It is also used for cellulose esters, cellulose ethers, synthetic resin and rubber solvent and polyester fibers to assist in the preparation of flavor. 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Scientific literature review of Benzyl alcohol, benzaldehyde, benzoic acid and related compounds. Safety and effectiveness of cefixime in children aged less than six months old have not been established. Trade Alert - Delivering the latest product trends and industry news straight to your inbox. Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. 20 g) of crushed ice held in a beaker. Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. Methyl benzoate CAS-No. Heat is also generated by the interaction of esters with caustic solutions. : 100223 Brand : Millipore REACH No. Avoid formation of dust and aerosols. Oral: LD50 - rat (male/female) - 2 000 mg/kg bw. Vapors can accumulate in low areas. . Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). endobj
Consolidate learning about simple displacement reactions with this game, followed by a formative assessment activity for the whole class, Five steps to confidence for your post-16 learners, How chemistry provides oxygen for breathing in emergency situations, Present and prastice a technique to help learners understand the language used in extended-reponse questions and improve their answers, Review your learners understanding of electrochemistryand its applications, Develop your learners metacognitive skills using thermodynamics questions and calculations, The physics of restoration and conservation, RSC Yusuf Hamied Inspirational Science Programme, How to prepare for the Chemistry Olympiad, Nitration of methyl benzoate - student sheet, (c) mechanism of electrophilic substitution, such as in the nitration, halogenation and Friedel-Crafts alkylation of benzene, as the characteristic reaction of arenes, Unit A2 1: Further Physical and Organic Chemistry. 0000014551 00000 n
Uses advised against Food, drug, pesticide or biocidal product use. Do not let product enter drains. Future Technologies L.L.C The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.)
CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". Methyl hydroxybenzoate (E218)1mg/5ml. Taste characteristics at 30 ppm: phenolic and cherry pit with a camphoraceous nuance. Identification Product Name Ethyl benzoate Cat No. Target Organs: None known. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. USA.gov. It does not represent any guarantee of the properties of the product. 4 0 obj
Tabulated list of adverse reactions. (USCG, 1999). Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Inhalation: Marketing authorisation number(s) 9. 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. The most commonly reported adverse reaction during treatment is pruritus. <>
: AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . P264 - P270 - P301 + P312 - P501. product with regard to appropriate safety precautions. Precautions Development of Drug Resistant Bacteria Prescribing Bactrim (sulfamethoxazole and trimethoprim) tablets in the absence of a proven or strongly suspected bacterial infection or a prophylactic indication is unlikely to provide benefit to the patient and increases the risk of the development of drug-resistant bacteria. Set up emergency exits and the risk-elimination area. P376: Stop leak if safe to do so. <<
Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. when exposed to heat or flame; can react SAFETY DATA SHEET Version 4.7 Revision Date 07/03/2014 Print Date 08/12/2014 1. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . GHS07. Esters react with acids to liberate heat along with alcohols and acids. Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Allow this mixture to cool. It is functionally related to a gamma-aminobutyric acid. Use safety glasses or safety goggles if splash hazards exist; use gloves and other protective clothing (apron, boots etc.) A crystalline solid or a solid dissolved in a liquid. 0000001433 00000 n
: 99-76-3 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Organic acids and related compounds. Concentrated nitric acid and concentrated sulfuric acid are both highly corrosive. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. <>
It does not represent any guarantee of the properties of the product. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. iQuLyI4D@yq#u0PbWu=rM?QUz{K6by_C"vW~Nj$bo? Supplier uploads its business license firstly. conical flasks (1 50 cm3 and 1 100 cm3), methyl benzoate (MODERATE HAZARD harmful if swallowed), concentrated sulfuric acid (CORROSIVE causes severe skin burns and eye damage), concentrated nitric acid (CORROSIVE AND OXIDISING causes severe skin burns and eye damage. Special Hazards of Combustion Products: None (USCG, 1999). If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
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